A Zwitterionic Alkaloid fromDaphniphyllum TeijsmanniZollinger

A highly selective receptor for zwitterionic proline.

A chiral chromane receptor has been synthesized which mimics the oxyanion hole of the enzymes. In this receptor H-bonds and cation-π interactions team up to generate an apolar host-guest complex with zwitterionic proline. This complex allows the extraction of only proline to a chloroform phase, while no other natural amino acids are extracted. Due to the chiral nature of the receptor, enantiose...

Zwitterionic co - crystals

Zwitterionic co-crystals family could be basis for very different structural and theoretical examinations as their ability to alter solubility and deliver a wide solubility spectrum is receiving more attention. Many zwitterionic co-crystals crystal structures exhibited carboxylate-hydroxyl supramolecular heterosynthons preference. In addition to examples of zwitterionic co-crystals in the Cambr...

A NEW ALKALOID FROM FLOWERS OF ERYTHRINA STRICTA

The alkaloids present in the flowers of Erythrina stricta have been isolated and characterized by spectroscopic methods. A new alkaloid 11-acetyl erysotrine has been isolated and its structure established by spectral studies (UV, IR, 1H NMR and HRMS).

Cinchona Alkaloid

Anthriscifolcine A, a C18-diterpenoid alkaloid

The title compound, C(26)H(39)NO(7), which was isolated from Delphinium anthriscifolium var. majus, has a lycoctonine carbon skeleton containing four six-membered rings (A, B, D and E) and three five-membered rings (C, F and G). Rings A, B and E adopt chair conformation, while ring D adopts a boat conformation. Rings C and F adopt envelope conformations.